Tabla de Contenidos: “…Cover -- Title Page 1 -- Copyright Page 2 -- About the Authors 3 -- Contents 5 -- Preface 25 -- 1 STRUCTURE AND BONDING 37 -- 1-1 The Origins of Organic Chemistry 37 -- 1-2 Principles of Atomic Structure 39 -- 1-3 Bond Formation: The Octet Rule 43 -- 1-4 Lewis Structures 44 -- 1-5 Multiple Bonding 45 -- Summary: Common Bonding Patterns (Uncharged) 45 -- 1-6 Electronegativity and Bond Polarity 46 -- 1-7 Formal Charges 47 -- 1-8 Ionic Structures 49 -- 1-9 Resonance 50 -- PROBLEM-SOLVING STRATEGY: Drawing and Evaluating Resonance Forms 54 -- 1-10 Structural Formulas 58 -- 1-11 Molecular Formulas and Empirical Formulas 61 -- 1-12 Wave Properties of Electrons in Orbitals 63 -- 1-13 Molecular Orbitals 64 -- 1-14 Pi Bonding 67 -- 1-15 Hybridization and Molecular Shapes 68 -- 1-16 Drawing Three-Dimensional Molecules 72 -- 1-17 General Rules of Hybridization and Geometry 73 -- Summary: Hybridization and Geometry 73 -- 1-18 Bond Rotation 78 -- 1-19 Isomerism 80 -- Essential Terms 83 -- Study Problems 86 -- 2 ACIDS AND BASES -- FUNCTIONAL GROUPS 91 -- 2-1 Polarity of Bonds and Molecules 92 -- 2-2 Intermolecular Forces 96 -- 2-3 Polarity Effects on Solubilities 100 -- 2-4 Arrhenius Acids and Bases 103 -- 2-5 Brønsted-Lowry Acids and Bases 104 -- 2-6 Strengths of Acids and Bases 105 -- 2-7 Equilibrium Positions of Acid-Base Reactions 109 -- PROBLEM-SOLVING STRATEGY: Predicting Acid-Base Equilibrium Positions 111 -- 2-8 Solvent Effects on Acidity and Basicity 112 -- Summary: Acidity and Basicity Limitations in Common Solvents 114 -- 2-9 Effects of Size and Electronegativity on Acidity 114 -- 2-10 Inductive Effects on Acidity 116 -- 2-11 Hybridization Effects on Acidity 117 -- 2-12 Resonance Effects on Acidity and Basicity 119 -- 2-13 Lewis Acids and Bases 122 -- 2-14 The Curved-Arrow Formalism 124 -- 2-15 Hydrocarbons 126.…”

Tabla de Contenidos: “…Cover -- Title Page -- Copyright Page -- Preface -- ACKNOWLEDGMENTS -- About the Author -- Contents -- PART ONE: An Introduction to the Study of Organic Chemistry -- 1 Remembering General Chemistry: Electronic Structure and Bonding -- CHEMICAL CONNECTION: Natural versus Synthetic Organic Compounds -- 1.1 The Structure of an Atom -- 1.2 How the Electrons in an Atom are Distributed -- 1.3 Covalent Bonds -- 1.4 How the Structure of a Compound is Represented -- PROBLEM-SOLVING STRATEGY -- 1.5 Atomic Orbitals -- 1.6 An Introduction to Molecular Orbital Theory -- 1.7 How Single Bonds are Formed in Organic Compounds -- 1.8 How a Double Bond is Formed: The Bonds in Ethene -- CHEMICAL CONNECTION: Diamond, Graphite, Graphene, and Fullerenes: Substances that Contain Only Carbon Atoms -- 1.9 How a Triple Bond is Formed: The Bonds in Ethyne -- 1.10 The Bonds in the Methyl Cation, the Methyl Radical, and the Methyl Anion -- 1.11 The Bonds in Ammonia and in the Ammonium Ion -- 1.12 The Bonds in Water -- CHEMICAL CONNECTION: Water-A Unique Compound -- 1.13 The Bond in a Hydrogen Halide -- 1.14 Hybridization and Molecular Geometry -- PROBLEM-SOLVING STRATEGY -- 1.15 Summary: Hybridization, Bond Lengths, Bond Strengths, and Bond Angles -- PROBLEM-SOLVING STRATEGY -- 1.16 Dipole Moments of Molecules -- ESSENTIAL CONCEPTS -- PROBLEMS -- 2 Acids and Bases: Central to Understanding Organic Chemistry -- 2.1 An Introduction to Acids and Bases -- 2.2 pK[Sub(a)] and pH -- PROBLEM-SOLVING STRATEGY -- CHEMICAL CONNECTION: Acid Rain -- 2.3 Organic Acids and Bases -- BIOLOGICAL CONNECTION: Poisonous Amines -- PROBLEM-SOLVING STRATEGY -- 2.4 How to Predict the Outcome of an Acid-Base Reaction -- 2.5 How to Determine the Position of Equilibrium -- 2.6 How the Structure of an Acid Affects its pK[Sub(a)] Value -- 2.7 How Substituents Affect the Strength of an Acid…”

Materias: “…Organic chemistry…”

“…With a focus on organic chemistry students at all levels, problems are incorporated into the body of the text in an effort to engage students more directly in chemistry…”

“…Organic Chemistry Frontiers is a high impact journal publishing work on all disciplines of organic chemistry. …”

“…Organic Chemistry Insights…”
Acceso restringido, con credenciales UPSA

Materias: “…Chemistry|Organic chemistry|Science|Sciences…”
Acceso restringido, con credenciales UPSA

Materias: “…Chemistry|Organic chemistry|Science|Sciences…”
Acceso restringido, con credenciales UPSA