Handbook of aqueous electrolyte thermodynamics theory & application
Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable ""do-it-yourself"" guide, with a blueprint for...
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| Formato: | Libro electrónico |
| Idioma: | Inglés |
| Publicado: |
New York, N.Y. :
Design Institute for Physical Property Data sponsored by the American Institute of Chemical Engineers
c1986.
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| Materias: | |
| Ver en Biblioteca Universitat Ramon Llull: | https://discovery.url.edu/permalink/34CSUC_URL/1im36ta/alma991009665120406719 |
Tabla de Contenidos:
- Handbook of Aqueous Electrolyte Thermodynamics Theory & Application; TABLE OF CONTENTS; I INTRODUCTION; II THERMODYNAMICS OF SOLUTIONS; Basic Thermodynamic Functions; Solutions - Basic Definitions and Concepts; Equilibrium - Necessary Conditions; Activities, Activity Coefficients and Standard States; III EQUILIBRIUM CONSTANTS; Ionic and/or Reaction Equilibrium in Aqueous Solutions; Solubility Equilibria Between Crystals and Saturated Solutions; Vapor-Liquid Equilibria in Aqueous Solutions; Temperature Effects on the Equilibrium Constant
- Estimating Temperature Effects on Heat Capacity and Other Thermodynamic PropertiesEquilibrium Constants from Tabulated Data; Pressure Effects on the Equilibrium Constant; Appendix 3.1 - Criss and Cobble Parameters; IV ACTIVITY COEFFICIENTS OF SINGLE STRONG ELECTROLYTES; History; Limitations and Improvements to the Debye-Huckel Limiting Law; Further Refinements; Bromley's Method; Meissner's Method; Pitzer's Method; Chen's Method; Short Range Interaction Model; Long Range Interaction Model; Temperature Effects; Bromley's Method; Meissner's Method; Pitzer's Method; Chen's Method; Application
- Bromley's MethodMeissner's Method; Pitzer's Method; Chen's Method; NBS Smoothed Experimental Data; Test Cases:; HCl; KCl; KOH; NaCl; NaOH; CaCl2; Na2SO4; MgSO4; Bromley's Extended Equation; MgSO4 Test Case; Comparison of Temperature Effect Methods; Bromley; Meissner; Pitzer and Chen; Experimental Data; Test Cases:; HCl at 50° Celsius; KCl at 80° Celsius; KOH at 80° Celsius; NaCl at 100 and 300° Celsius; NaOH at 35° Celsius; CaCl2 at 108.85 and 201.85° Celsius; Na2SO4 at 80° Celsius; MgSO4 at 80° Celsius; Appendix 4.1 - Values for Guggenheim's β Parameter
- Table 1: β Values for Uni-univalent ElectrolytesTable 2: β and B Values of Bi-univalent and Uni-bivalent Electrolytes from Freezing Points; Methods for Calculating β; Appendix 4.2 - Bromley Interaction Parameters; Table 1: B Values at 25°C Determined by the Method of Least Squares on Log γ to I=6.0 (or less if limited data); Table 2: Individual Ion Values of B and δ in Aqueous Solutions at 25°C; Table 3: Bivalent Metal Sulfates at 25°C; Appendix 4.3 - Meissner Parameters; Table: Average Values of Parameter q in Equation (4.46) for Selected Electrolytes; Appendix 4.4 - Pitzer Parameters
- Table 1: Inorganic Acids, Bases and Salts of 1-1 TypeTable 2: Salts of Carboxylic Acids (1-1 Type); Table 3: Tetraalkylammonium Halides; Table 4: Sulfonic Acids and Salts (1-1 Type); Table 5: Additional 1-1 Type Organic Salts; Table 6: Inorganic Compounds of 2-1 Type; Table 7: Organic Electrolytes of 2-1 Type; Table 8: 3-1 Electrolytes; Table 9: 4-1 Electrolytes; Table 10: 5-1 Electrolytes; Table 11: 2-2 Electrolytes; Appendix 4.5 - Pitzer Parameter Derivatives; Table 1: Temperature Derivatives of Parameters for 1-1 Electrolytes Evaluated from Calorimetric Data
- Table 2: Temperature Derivatives of Parameters for 2-1 and 1-2 Electrolytes Evaluated from Calorimetric Data
