Handbook of polymer solution thermodynamics
Created for engineers and students working with pure polymers and polymer solutions, this handbook provides up-to-date, easy to use methods to obtain specific volumes and phase equilibrium data. A comprehensive database for the phase equilibria of a wide range of polymer-solvent systems, and PVT beh...
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| Formato: | Libro electrónico |
| Idioma: | Inglés |
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New York :
Design Institute for Physical Property Data, American Institute of Chemical Engineers
c1993.
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| Ver en Biblioteca Universitat Ramon Llull: | https://discovery.url.edu/permalink/34CSUC_URL/1im36ta/alma991009665112406719 |
Tabla de Contenidos:
- Handbook Of Polymer Solution Thermodynamics; TABLE OF CONTENTS; PREFACE; Chapter 1 : INTRODUCTION; A. OBJECTIVES OF THE HANDBOOK OF POLYMER SOLUTION THERMODYNAMICS; Chapter 2: FUNDAMENTALS OF POLYMER SOLUTION THERMODYNAMICS; A. PURE POLYMER PVT BEHAVIOR; B. PHASE EQUILIBRIA THERMODYNAMICS; C. MODELING APPROACHES TO POLYMER SOLUTION THERMODYNAMICS; D. LATTICE MODELS; 1. Flory-Huggins Model; 2. Solubility Parameters and the Flory-Huggins Model; 3. Modifications of the Flory-Huggins Model; 4. Sanchez-Lacombe Equation of State; 5. Panayiotou-Vera Equation of State; 6. Kumar Equation of State
- 7. High-Danner Equation of State8. Oishi-Prausnitz Activity Coefficient Model; E. VAN DER WAALS MODELS; 1. Flory Equation of State; 2. Chen, Fredenslund, and Rasmussen Equation of State; F. LIQUID-LIQUID EQUILIBRIA OF POLYMER SOLUTIONS; 1. Thermodynamics of Liquid-Liquid Equilibria; 2. Types of Liquid-Liquid Equilibria; 3. Models for Liquid-Liquid Equilibria; 4. Computation of Liquid-Liquid Equilibria Compositions; 5. Parameter Estimation from Liquid-Liquid Equilibria Data; 6. Sample Correlations of Liquid-Liquid Equilibria Data; G. EFFECT OF POLYDISPERSION; Chapter 3: RECOMMENDED PROCEDURES
- A. SELECTION OF MODELS1. Correlation of Pure Polymer PVT Behavior; 2. Prediction of Vapor-Liquid Equilibria; B. PROCEDURE: METHOD FOR ESTIMATING THE SPECIFIC VOLUME OF A PURE POLYMER LIQUID; 1. Method; 2. Procedure; 3. Limitations and Reliability; 4. Comments; 5. Literature Sources; 6. Example; C. PROCEDURE: OISHI-PRAUSNITZ METHOD FOR ESTIMATING THE ACTIVITY COEFFICIENTS OF SOLVENTS IN POLYMER SOLUTIONS; 1. Method; 2. Procedure; 3. Limitations and Reliability; 4. Comments; 5. Literature Sources; 6. Example
- D. PROCEDURE: CHEN-FREDENSLUND-RASMUSSEN EQUATION OF STATE FOR ESTIMATING THE ACTIVITY COEFFICIENTS OF SOLVENTS IN POLYMER SOLUTIONS1. Method; 2. Procedure; 3. Limitations and Reliability; 4. Literature Source; 5. Example; E. PROCEDURE: HIGH-DANNER EQUATION OF STATE FOR ESTIMATING THE ACTIVITY COEFFICIENT OF A SOLVENT IN A POLYMER SOLUTION; 1. Method; 2. Procedure; 3. Limitations and Reliability; 4. Literature Sources; 5. Example; F. PROCEDURE: FLORY-HUGGINS CORRELATION FOR VAPOR-LIQUID EQUILIBRIA OF POLYMER SOLVENT SYSTEMS; 1. Method; 2. Procedure; 3. Limitiations and Reliability
- 4. Literature Source5. Example; Chapter 4: POLYMER DATA BASE; A. INTRODUCTION; B. EXPERIMENTAL METHODS; 1. Inverse Gas Chromatography (IGC); 2. Piezoelectric Sorption (PZS); 3. Differential Vapor Pressure (DVP); 4. Gravimetric Sorption (GS); 5. Light Scattering (LS); 6. Ultracentrifuge (UC); 7. Turbidimetry (TB) and Light Scattering Turbidimetry (LST); 8. Microanalytical (MA); 9. Ultraviolet Spectrometry (UVS) and Infrared Spectrometry (1RS); 10. Size Exclusion Chromatography (SEC); C. DATA REDUCTION PROCEDURES; 1. Pure Polymer PVT Data; 2. Finite Dilution Flory Chi Parameter
- 3. Infinite Dilution Flory Chi Parameter
