σ- and π-Hole Interactions

This book describes unconventional noncovalent interactions and analyzes their importance for crystal growth in organic and hybrid organic–inorganic systems. Several examples illustrate how the combination of theory and experiment allows rationalizing the strength and directionality of noncovalent i...

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Detalles Bibliográficos
Otros Autores:	Frontera, Antonio (Editor)
Formato:	Libro electrónico
Idioma:	Inglés
Publicado:	Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2021
Materias:	Research & information: general Biology, life sciences non-covalent interactions regium bonds silver(I) coinage metals pyrazolates phosphines halogen bonding hydrogen bonding sigma-hole interactions theoretical studies characterizations noncovalent interactions Lewis acids Lewis bases spodium bonds σ/π-hole interactions EDTA 2,6-diaminopurine cadmium co-crystal H-bonding π–π stacking triazinane 1,3,5-Triazacyclohexane Hirshfeld surface analysis DFT study C–H···π interaction hybridization of a nitrogen atom in sulfonamides molecular cocrystal sandwiched-layer structure C–I···F halogen bonds π···π stacking interactions PBE0-D3(BJ) calculations secondary bonding supramolecular crystal engineering tetrel bonding pnictogen bonding chalcogen bonding selenium structural chemistry main group elements π–hole interaction substituent effects vibrational spectroscopy local vibrational mode theory direct measure for π–hole interaction strength noncovalent interaction hydrogen bonding nickel Schiff bases crystallography σ-hole π-hole crystal growth supramolecular chemistry σ-hole interactions self-assembly scanning tunneling microscopy
Ver en Biblioteca Universitat Ramon Llull:	https://discovery.url.edu/permalink/34CSUC_URL/1im36ta/alma991009654965106719