Sumario: | Strongly correlated electron systems are among the most active research topics in modern condensed matter physics. In strongly correlated materials the electron interaction energies dominate the electron kinetic energy which leads to unconventional properties ... Strong electronic correlations are responsible for physical phenomena on a low energy scale. Consequently, these phenomena have to be studied at low temperatures. This, in turn, requires ultimate quality of single crystals to avoid that the low temperature intrinsic properties are covered by extrinsic effects due to off-stoichiometry, impurities or other crystal imperfections ... Much attention in this paper is paid to the problem of stoichiometry. Single crystals of intermetallic compounds are grown at high temperatures, which facilitates the formation of thermal defects realized often as deviation from the stoichiometric composition. Thermal instabilities of some intermetallic phases require the use of flux techniques, i.e., growth from off-stoichiometric melts, which is another source of non-stoichiometry. Sizeable non-stoichiometries can be detected by measuring the composition by chemical and physical analytical techniques, e.g. energy dispersive X-ray spectroscopy analysis (EDX). Tiny deviations from the stoichiometry, on the other hand, can be found only from an analysis of the physical properties of single crystals. Thus physical property measurements are not only the final purpose of a crystal growth but also a valuable diagnostic tool for further improvement of their quality. Therefore, in the paper the consideration of crystal growth is accompanied by the discussion of their physical properties.
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