Hydrogen storage technologies
Hydrogen storage is considered a key technology for stationary and portable power generation especially for transportation. This volume covers the novel technologies to efficiently store and distribute hydrogen and discusses the underlying basics as well as the advanced details in hydrogen storage...
| Otros Autores: | , |
|---|---|
| Formato: | Libro electrónico |
| Idioma: | Inglés |
| Publicado: |
Hoboken, NJ : Beverly, MA :
Wiley
2018.
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| Edición: | 1st edition |
| Colección: | Advances in hydrogen production and storage
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| Materias: | |
| Ver en Biblioteca Universitat Ramon Llull: | https://discovery.url.edu/permalink/34CSUC_URL/1im36ta/alma991009630418506719 |
Tabla de Contenidos:
- Cover
- Title Page
- Copyright Page
- Contents
- Preface
- Part I: Chemical and Electrochemical Hydrogen Storage
- 1 Metal Hydride Hydrogen Compression Systems - Materials, Applications and Numerical Analysis
- 1.1 Introduction
- 1.2 Adoption of a Hydrogen-Based Economy
- 1.2.1 Climate Change and Pollution
- 1.2.2 Toward a Hydrogen-Based Future
- 1.2.3 Hydrogen Storage
- 1.2.3.1 Compressed Hydrogen Storage
- 1.2.3.2 Hydrogen Storage in Liquid Form
- 1.2.3.3 Solid-State Hydrogen Storage
- 1.3 Hydrogen Compression Technologies
- 1.3.1 Reciprocating Piston Compressor
- 1.3.2 Ionic Liquid Piston Compressor
- 1.3.3 Piston-Metal Diaphragm Compressor
- 1.3.4 Electrochemical Hydrogen Compressor
- 1.4 Metal Hydride Hydrogen Compressors (MHHC)
- 1.4.1 Operation of a Two-Stage MHHC
- 1.4.2 Metal Hydrides
- 1.4.3 Thermodynamic Analysis of the Metal Hydride Formation
- 1.4.3.1 Pressure-Composition-Temperature (P-c-T) Properties
- 1.4.3.2 Slope and Hysteresis
- 1.4.4 Material Challenges for MHHCs
- 1.4.4.1 AB5 Intermetallics
- 1.4.4.2 AB2 Intermetallics
- 1.4.4.3 TiFe-Based AB-Type Intermetallics
- 1.4.4.4 Vanadium-Based BCC Solid Solution Alloys
- 1.5 Numerical Analysis of a Multistage MHHC System
- 1.5.1 Assumptions
- 1.5.2 Physical Model and Geometries
- 1.5.3 Heat Equation
- 1.5.4 Hydrogen Mass Balance
- 1.5.5 Momentum Equation
- 1.5.6 Kinetic Expressions for the Hydrogenation and Dehydrogenation
- 1.5.7 Equilibrium Pressure
- 1.5.8 Coupled Mass and Energy Balance
- 1.5.9 Validation of the Numerical Model
- 1.5.10 Material Selection for a Three-Stage MHHC
- 1.5.11 Temperature Evolution of the Complete Three-Stage Compression Cycle
- 1.5.12 Pressure and Storage Capacity Evolution During the Complete Three-Stage Compression Cycle
- 1.5.13 Importance of the Number of Stages and Proper Selection
- 1.6 Conclusions.
- Acknowledgments
- Nomenclature
- References
- 2 Nitrogen-Based Hydrogen Storage Systems: A Detailed Overview
- 2.1 Introduction
- 2.2 Amide/Imide Systems
- 2.2.1 Single-Cation Amide/Imide Systems
- 2.2.1.1 Lithium Amide/Imide
- 2.2.1.2 Sodium Amide/Imide
- 2.2.1.3 Magnesium Amide/Imide
- 2.2.1.4 Calcium Amide/Imide
- 2.2.2 Double-Cation Amide/Imide Systems
- 2.2.2.1 Li-Na-N-H
- 2.2.2.2 Li-Mg-N-H
- 2.2.2.3 Other Double-Cation Amides/Imides
- 2.3 Ammonia (NH3) as Hydrogen Storage Media
- 2.3.1 NH3 Synthesis
- 2.3.1.1 Catalytic NH3 Synthesis Using Haber-Bosch Process
- 2.3.1.2 Alternative Routes for NH3 Synthesis
- 2.3.2 NH3 Solid-State Storage
- 2.3.2.1 Metal Ammine Salts
- 2.3.2.2 Ammine Metal Borohydride
- 2.3.3 NH3 Decomposition
- 2.3.4 Application of NH3 to Fuel Cell
- 2.4 Future Prospects
- References
- 3 Nanostructured Mg-Based Hydrogen Storage Materials: Synthesis and Properties
- 3.1 Introduction
- 3.2 Experimental Details
- 3.2.1 Synthesis of Metal Nanoparticles
- 3.2.2 Formation of the Nanostructured Hydrides and Alloys
- 3.2.3 Characterization and Measurements
- 3.3 Synthesis Results of the Nanostructured Samples
- 3.4 Hydrogen Absorption Kinetics
- 3.5 Hydrogen Storage Thermodynamics
- 3.6 Novel Mg-TM (TM=V, Zn, Al) Nanocomposites
- 3.6.1 Introduction
- 3.6.2 Structure and Morphology of Mg-TM Nanocomposites
- 3.6.3 Hydrogen Absorption Kinetics
- 3.6.4 Phase Evolution During Hydrogenation/ Dehydrogenation
- 3.6.5 Summary
- 3.7 Summary and Prospects
- Acknowledgments
- References
- 4 Hydrogen Storage in Ti/Zr-Based Amorphous and Quasicrystal Alloys
- 4.1 Introduction
- 4.2 Production of Ti/Zr-Based Amorphous and Quasicrystals Alloys
- 4.3 Hydrogen Storage in T-Zr-Based Amorphous Alloys
- 4.3.1 Gaseous Hydrogenation
- 4.3.2 Electrochemical Hydrogenation.
- 4.4 Hydrogen Storage in the Ti/Zr-Based Quasicrystal Alloys
- 4.4.1 Gaseous Hydrogenation
- 4.4.2 Electrochemical Hydrogenation
- 4.5 Comparison of Amorphous and Quasicrystal Phases on the Hydrogen Properties
- 4.6 Conclusions
- References
- 5 Electrochemical Method of Hydrogenation/Dehydrogenation of Metal Hydrides
- 5.1 Introduction
- 5.2 Electrochemical Method of Hydrogenation of Metal Hydrides
- 5.2.1 Hydrogen Accumulation in Electrodes of Cadmium-Nickel Batteries Based on Electrochemical Method
- 5.2.2 Hydrogen Accumulation in Sintered Nickel Matrix of Oxide-Nickel Electrode
- 5.2.2.1 Active Substance of Oxide-Nickel Electrodes
- 5.2.2.2 Sintered Nickel Matrices of Oxide-Nickel Electrodes
- 5.3 Electrochemical Method of Dehydrogenation of Metal Hydrides
- 5.3.1 Introduction
- 5.3.2 Thermal Runaway as the New Method of Hydrogen Desorption from Hydrides
- 5.3.2.1 Thermo-Chemical Method of Hydrogen Desorption
- 5.3.2.2 Thermal Runaway: A New Method of Hydrogen Desorption from Metal Hydrides
- 5.4 Discussion
- 5.5 Conclusions
- References
- Part II: Carbon-Based Materials For Hydrogen Storage
- 6 Activated Carbon for Hydrogen Storage Obtained from Agro-Industrial Waste
- 6.1 Introduction
- 6.2 Experimental
- 6.3 Results and Discussion
- 6.4 Conclusions
- Acknowledgments
- References
- 7 Carbonaceous Materials in Hydrogen Storage
- 7.1 Introduction
- 7.2 Materials Consisting of Only Carbon Atoms
- 7.2.1 Graphite
- 7.2.2 Carbon Nanofibers
- 7.2.3 Carbon Nanostructures
- 7.2.4 Graphene
- 7.2.5 Carbon Nanotubes (CNTs) and Carbon Multi-Walled Nanotubes (MWCNTs)
- 7.3 Materials Containing Carbon and Other Light Elements
- 7.3.1 Polyaniline (PANI), Polypyrrole (PPy) and Polythiophene (PTh)
- 7.3.2 Hyperbranched Polyurea (P-Urea) and Poly(Amide-Amine) (PAMAM)
- 7.3.3 Microporous Polymers (PIMs).
- 7.3.4 Conjugated Microporous Polymers (CMPs)
- 7.3.5 Hyper-Cross-Linked Polymers (HCPs)
- 7.3.6 Porous Aromatic Frameworks (PAFs)
- 7.4 Composite Materials Made by Polymeric Matrix
- 7.4.1 Composite Poly(Amide-Amine) (PAMAM)
- 7.4.2 Polymer-Dispersed Metal Hydrides (PDMHs)
- 7.4.3 Mn Oxide Anchored to a Polymeric Matrix
- 7.5 Waste and Natural Materials
- 7.6 Conclusions
- References
- 8 Beneficial Effects of Graphene on Hydrogen Uptake and Release from Light Hydrogen Storage Materials
- 8.1 Introduction
- 8.2 General Aspects of Graphene
- 8.2.1 Synthesis of Graphene
- 8.2.1.1 Mechanical Cleavage of Highly Oriented Pyrolytic Graphite
- 8.2.1.2 Chemical Vapor Deposition
- 8.2.1.3 Chemical and Thermal Exfoliation of Graphite Oxide
- 8.2.1.4 Arc Discharge Method
- 8.2.2 Graphene as a Beneficial Additive for HS Materials
- 8.3 Beneficial Effect of Graphene: Key Results with Light Metal Hydrides (e.g., LiBH4, NaAlH4, MgH2)
- 8.3.1 Borohydrides (Tetrahydroborate) as HS Material
- 8.3.1.1 Effect of Graphene on Desorption Properties of LiBH4
- 8.4 Alanates as HS Materials
- 8.4.1 Effect of Graphene on Sorption Behavior of NaAlH4
- 8.4.2 Carbon Nanomaterial-Assisted Morphological Tuning of NaAlH4 to Improve Thermodynamics and Kinetics
- 8.5 Magnesium Hydride as HS Material
- 8.5.1 Catalytic Effect of Graphene on Sorption Behavior of Mg/MgH2
- 8.5.2 Nanoparticles Templated Graphene as an Additive for MgH2
- 8.6 Summary and Future Prospects
- Acknowledgment
- References
- 9 Hydrogen Adsorption on Nanotextured Carbon Materials
- 9.1 Introduction
- 9.1.1 Essential Features of Hydrogen Adsorption on Porous Carbon Materials
- 9.1.2 Measurement of the Hydrogen Storage Capacity
- 9.1.3 Excess, Absolute and Total Hydrogen Adsorption
- 9.2 Hydrogen Storage in Carbon Materials
- 9.2.1 Activated Carbons
- 9.2.2 Carbon Nanomaterials.
- 9.2.2.1 Graphene
- 9.2.2.2 Fullerenes
- 9.2.2.3 Carbon Nanotubes
- 9.2.2.4 Carbon Nanofibers
- 9.2.3 Templated Carbons
- 9.2.3.1 Zeolite- and Silica-Derived Carbons
- 9.2.3.2 MOFs-Derived Carbons
- 9.2.4 Other Carbon Materials
- 9.2.4.1 Carbide-Derived Carbons
- 9.2.4.2 Hybrid Carbon-MOF Materials
- 9.2.4.3 Hyper-Cross-Linked Polymers-Derived Carbons
- 9.2.4.4 Carbon Nanorods, Nanohorns and Nanospheres
- 9.2.4.5 Carbon Nitrides
- 9.2.4.6 Carbon Aerogels
- 9.2.4.7 Other Exotic Carbon Materials
- 9.3 Conclusion
- Acknowledgments
- References
- Appendix
- Index
- EULA.
