Supercritical fluids and organometallic compounds from recovery of trace metals to synthesis of nanostructured materials
Organometallic compounds are utilized as reagents in the preparation and processing of advanced nanostructured materials, as catalysts in the production of a wide variety of specialty chemicals and polymers, and as drugs. Supercritical fluid science and technology has a wide variety of applications...
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| Format: | eBook |
| Language: | Inglés |
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Amsterdam :
Elsevier
2011.
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| Series: | Supercritical fluid science and technology ;
v. 1. |
| Subjects: | |
| See on Biblioteca Universitat Ramon Llull: | https://discovery.url.edu/permalink/34CSUC_URL/1im36ta/alma991009627887606719 |
Table of Contents:
- Front Cover; Supercritical Fluids and Organometallic Compounds: From Recovery of Trace Metals to Synthesis of Nanostructured Materials; Copyright; Contents; Foreword; Preface; Chapter 1: Introduction to Coordination Compounds; 1.1. Introduction; 1.2. Types of Coordination Compounds; 1.3. Structure and Bonding in Coordination of Compounds; 1.4. Reactions of Organometallic Compounds; References; Chapter 2: Fundamental Aspects of Supercritical Fluids; References; Chapter 3: Thermodynamics of Mixtures of Metal Complexes with Supercritical Fluids; 3.1. Phase behavior
- 3.2. Techniques to measure solubilities of metal complexes in SCFs3.3. Solubilities of metal complexes in scCO2; 3.4. Correlation of solubilities; References; Chapter 4: Thermodynamics and Dynamics of Adsorption of Metal Complexes on Surfaces from Supercritical Solutions; 4.1. Adsorption; 4.1.1. Physisorption; 4.1.2. Chemisorption; 4.2. Adsorption isotherms; 4.2.1. Adsorption Isotherm Models; 4.2.2. The Langmuir Model; 4.2.3. The Freundlich Model; 4.3. Adsorption of SCFs; 4.4. Adsorption of solutes from supercritical mixtures; 4.5. Adsorption of metal complexes on surfaces
- 4.5.1. Experimental Techniques for Determination of Adsorption Isotherms4.5.1.1. Batch Adsorption; 4.5.1.2. Frontal Analysis Chromatography; 4.5.1.3. Pulse Chromatography; 4.5.2. Adsorption Isotherms for Metal Complex-Adsorbent-scCO2 Systems; 4.5.3. Kinetics of Adsorption of Metal Complexes on Porous Substrates from Supercritical Solutions; References; Chapter 5: Synthesis of Nanostructured Composites of Metals; 5.1. Supported nanoparticles on inorganic and carbon supports; 5.2. Polymer-Supported Nanoparticles; 5.3. Supported Bimetallic Nanoparticles; 5.4. Metallic Films; References
- Chapter 6: Extraction of Metals Using Supercritical Fluids6.1. Solvent extraction of metals; 6.2. SCF extraction of metals; 6.2.1. SCF Extraction with Cation Exchangers; 6.2.2. SCF Extraction with Solvating Extractants; 6.2.3. SCF Extraction with Liquid Anion Exchangers and Crown Ethers; 6.3. Experimental methods; 6.4. Back extraction or stripping; 6.5. Kinetics of extraction; 6.6. Extraction of Metals from Solid Matrices; References; Chapter 7: Homogeneous Catalysis in Supercritical Fluids; 7.1. Homogeneous catalysis in supercritical fluids
- 7.1.1. Advantages of Using SCFs in Homogeneous Catalysis7.1.2. Ligand Modification for Solubility Enhancement; 7.1.3. Experimental Techniques to Study Homogeneous Catalytic Reactions in SCFs; 7.2. Applications of homogeneous catalysis in supercritical fluids; 7.2.1. Hydroformylation; 7.2.1.1. Current Industrial Applications of Hydroformylation; 7.2.1.2. Hydroformylation in SCFs; 7.2.1.3. Fundamental Studies on Hydroformylation in SCFs; The Nature of 1 in Carbon Dioxide; Reaction of 1 with Carbon Monoxide in Carbon Dioxide; Reaction of 1 with Carbon Monoxide/Hydrogen in Carbon Dioxide
- Reaction of 1 with Carbon Monoxide and Ethylene in Carbon Dioxide
