Electrochemical reactions and mechanisms in organic chemistry
Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more ""green"" chemical synthesis. Over recent years, modern investigations have clarified the mechani...
| Autor principal: | |
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| Formato: | Libro electrónico |
| Idioma: | Inglés |
| Publicado: |
Amsterdam ; New York :
Elsevier
2000.
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| Edición: | 1st ed |
| Materias: | |
| Ver en Biblioteca Universitat Ramon Llull: | https://discovery.url.edu/permalink/34CSUC_URL/1im36ta/alma991009627137406719 |
Tabla de Contenidos:
- Front Cover; Electrochemical Reaction and Mechanisms in Organic Chemistry; Copyright Page; Contents; Chapter 1. Electrochemical Oxidation and Reduction of Organic Compounds; General Technique; Anode arid Cathode Materials; Kinetics of Electron Transfer; Analytical arid Spectroscopic Techniques; Pulse Radiolysis; Chapter 2. Oxidation of Alkanes, Haloalkanes and Alkenes; Radical- Cations; Oxidation of Alkanes; Oxidation of Haloalkanes; Oxidation of Alkenes; Intramolecular Cyclization; Electrochemically Generated Reagents for Alketies; Chapter 3. Alkenes and Conjugated Alkenes, Reduction
- Alkenes and PhenylalkenesAlketie Radical-Anions as Nucleophiles; Activated Alketies - Introduction; Activated Alketies - Dimerization in Aprotic Media; Activated Alkenes - Dimerization in Protic Media; α,β-Unsaturated Aldehydes and Ketones; Intramolecular Cyclization; Mixed Hydrocoupling Reactions; Asymmetric Reduction; Electrocatalytic Hydrogenation; Chapter 4. Reductive Bond Cleavage Processes - I; Dissociative Electron Transfer; Reduction of Alkyl and Benzyl Halides; Reactions of the Trichloromethyl Group; Reductive Cyclization of α, ω-Dihaloalkanes
- Alketies from 1,2-Dibromides and Related CompoundsReduction of Aryl Halides; Electrochemically Induced SRNl Reaction; Electrochemically Induced Radical Cyclization Reactions of Aryl Halides; Carbon-Halogen Bond Reactions Catalysed by the Anode Material; Carbon-Halogen Bond Reactions Catalysed by Ni, Co and Pd Complexes; Reactions with Carbon Dioxide; Chapter 5. Reductive Bond Cleavage Processes - II; Introduction; Carbotn-Oxygen Bond Cleavage; Quaternary Ammonium Salts; Quaternary Phosphonium and Arsonuim Salts; Carbon-Sulphur and Related Bond Cleavage
- Cleavage Assisted by an adjacent Carbonyl FunctionCarbon-Carbon Bond Cleavage; The Abnormal Clemmensen Reaction; Chapter 6. Oxidation of Aromatic Rings; Radical-Cations; Oxidative Substitution Reactions; Oxidation of Phenols; Intramolecular Cyclization Processes; Oxidation of Anilines; Oxidation of Aromatic Heterocycles; Chapter 7. Reduction of Aromatic Rings; Aromatic compounds Radical-Anions; Aromatic Hydrocarbon; Thiophene, Pyrrole and Indole Derivatives; Pyridine, Quinolne and Isoquinoline Derivatives; Other Nitrogen Heterocycles; Nitrogen-Nitrogen Bond cleavage
- Reductive Alkylation and CarboxylationElectrocatalytic Hydrogenation; Chapter 8. Alcohols, Amines and Amides, Oxidation; Nitroxyl Radicals; Oxidation of Alcohols; Oxidation of Amides and Sulphonamides; Oxidation of Amides and Urethanes; Oxidation of Hydrazine Derivatives; Chapter 9. Aldehydes, Ketones and Carboxylic Acids, Oxidation; Oxidation of Ketones; Oxidation of Aldehydes; Oxidation of Etiolate Ions; Oxidation of Hydrazones and Oximes; Oxiddon of Carboxylate - Introduction and Mechanism; The Kolbe Reaction; The Non- Kolbe Reaction
- Chapter 10. Reduction of Carbonyl Compounds and their Derivatives
