Design and applications of novel titanium and copper containing mesoporous organic-inorganic hybrid materials
| Autor principal: | |
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| Otros Autores: | , |
| Formato: | Libro electrónico |
| Idioma: | Castellano |
| Publicado: |
Madrid :
Dykinson
2011.
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| Colección: | Ciencias experimentales y tecnología ;
47. |
| Materias: | |
| Ver en Biblioteca Universitat Ramon Llull: | https://discovery.url.edu/permalink/34CSUC_URL/1im36ta/alma991009428570506719 |
Tabla de Contenidos:
- Design and applications of novel titanium and copper containing mesoporous organic-inorganic hybrid materials; Página legal; Contents; Index of Figures; Index of Tables; Index of Schemes; Chapter 1; 1.1 Catalysis; 1.2 Enantioselective Catalysis; 1.2.1 Chirality and Enantioselective Catalysis; 1.3 Catalytic Oxidation; 1.3.1 Olefin Epoxidation; 1.3.2 Applications of Epoxides; 1.3.3 Asymmetric Epoxidation; 1.3.4 Alcohol Oxidation; 1.4 Mesostructured Materials; 1.4.1 Organically Modification of Mesostructured Materials; 1.4.2 Grafting, Tethering and Framework Incorporation ofMetal Complexes
- 1.4.3 Heterogeneous Oxidation Catalysts1.4.3.1 Titanium-framework Substituted into HeterogeneousCatalysts; 1.4.3.2 Titanium- grafted or Tethered into Heterogeneous Catalysts; 1.4.3.3 Copper-grafted or Tethered into Heterogeneous Catalysts; 1.4.3.4 Copper-framework Substituted into HeterogeneousCatalysts; 1.5 References; Chapter 2; 2.1 Methodology; 2.2 Instrumentation Techniques; 2.2.1 Spectroscopic Techniques; 2.2.1.1 Ultraviolet and Visible Spectroscopy; 2.2.1.2 FT-Infrared Spectroscopy; 2.2.1.3 X-ray Diffraction Spectroscopy; 2.2.1.4 Atomic Emission Spectroscopy
- 2.2.1.5 Nuclear Magnetic Resonance Spectroscopy2.2.2 Other techniques; 2.2.2.1 Mass spectrometry; 2.2.2.2 Thermal Analysis (TGA); 2.2.2.3 Isotherm Adsorption; 2.2.2.4 Elemental Analysis; 2.2.2.5 Scanning Electron Micrographs (SEM) and Energy-Dispersive X-ray (EDX) Detector; 2.2.2.6 Transmission Electron Microscopy (TEM); 2.3 References; Chapter 3; 3.1 Introduction; 3.2 Results and Discussion; 3.2.1 Preparation and Characterization of Alkoxysilane Ligands; 3.2.1.1 Preparation and Characterization of 6-(3-(triethoxysilyl)propoxy)-1,3,5-triazine-2,4-diol (CyPTS)
- 3.2.1.2 Preparation and Characterization of N4-(3-(triethoxysilyl)propyl)pyrimidine-2,4,6-triamine(DAPyPTS)3.2.2 Preparation and Characterization of the MCM-41; 3.2.3 Preparation and Characterization of the FunctionalizedMaterials; 3.2.3.1 Preparation and Characterization of the MaterialsFunctionalized with CyPTS; 3.2.3.2 Preparation and Characterization of the MaterialsFunctionalized with DAPyPTS; 3.3 Experimental; 3.3.1 Reagents and Materials; 3.3.2 Synthesis of MCM-41 Mesoporous Silica; 3.3.3 Synthesis of the Organic Ligands
- 3.3.3.1 Synthesis of 6-(3-triethoxysilyl)propoxy)-1,3,5-triazine-2,4-diol, (CyPTS)3.3.3.2 Synthesis of N4-(3-(triethoxysilyl)propyl)pyrimidine-2,4,6-triamine, (DAPyPTS); 3.3.4 Functionalization of MCM-41; 3.3.4.1 Preparation of Modified MCM-41 with CyPTS Ligand andHMDS or MTMS as Capped Agents; 3.3.4.2 Functionalization of the MCM-41 with DAPyPTS Ligand; 3.4 Conclusions; 3.5 References; Chapter 4; 4.1 Introduction; 4.2 Results and Discussion; 4.2.1 Characterization of Titanium Tetraisopropoxide DerivatedHeterogeneous Catalysts
- 4.2.2 Characterization of Chiral Titanium tetraisopropoxidederivated heterogeneous catalysts
