87Sr/86Sr isotopic ratio Amarone Chianti Classico wine ICP-MS IRMS NMR Negro Amaro Primitivo Raboso Recioto Tannat wines authenticity bio-geochemical strategy data mining feature selection fingerprinting geographic origin geographical origin geographical traceability geological material grape grapevine varietal identification and discrimination high-resolution mass spectrometry isotopes markers metabolomics multi-element composition polyphenols rare earth elements red wine